3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission
نویسندگان
چکیده
منابع مشابه
3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission
Among luminescence techniques, electrogenerated chemiluminescence (ECL) provides a unique level of manipulation of the luminescent process by controlling the electrochemical trigger. Despite its attractiveness, ECL is by essence a 2D process where light emission is strictly confined to the electrode surface. To overcome this intrinsic limitation, we added a new spatial dimension to the ECL proc...
متن کاملElectrogenerated chemiluminescence from Au nanoclusters.
Electrogenerated chemiluminescence (ECL) of Au clusters is observed for the first time using triethyamine (TEA) as the coreactant. The potential application of ECL Au clusters in analytical chemistry is also demonstrated using Pb(2+) as an example.
متن کاملElectrogenerated chemiluminescence. 58. Ligand-sensitized electrogenerated chemiluminescence in europium labels.
The electrochemistry and electrogenerated chemiluminescence (ECL) of a series of europium chelates, cryptates, and mixed-ligand chelate/cryptand complexes were studied. The complexes were of the following general forms: EuL(4)(-), where L = β-diketonate, a bis-chelating ligand (such as dibenzoylmethide), added as salts (A)EuL(4), where A = tetrabutylammonium ion or piperidinium ion (pipH(+)); ...
متن کاملElectrogenerated chemiluminescence. 39. Reactions of solvated electrons in liquid ammonia
The Journal of Physical Chemistry is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 Electrogenerated chemiluminescence. 39. Reactions of solvated electrons in liquid ammonia Kingo Itaya, and Allen J. Bard J. Phys. Chem., 1981, 85 (10), 1358-1365• DOI: 10.1021/j150610a018 • Publication Date (Web): 01 May 2002 Downloaded from http://pubs.acs.org on Fe...
متن کاملElectrogenerated Chemiluminescence. 59. Rhenium Complexes
Re(L)(CO)3Cl complexes (where L is 1,10-phenanthroline, 2,2′-bipyridine, or a phenanthroline or bipyridine derivative containing methyl groups) are photoluminescent in fluid solution at room temperature. In acetonitrile solutions, these complexes display one chemically reversible one-electron reduction process and one chemically irreversible oxidation process. λmax for the luminescence is depen...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemical Science
سال: 2015
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c5sc01530h